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Ana has been drawn to face compatriot and No.5 seed Jelena Jankovic in the first round of the Porsche Tennis Grand Prix, which begins in Stuttgart on Monday.
12th-ranked Ana has missed out on a seeding by just one ranking spot, with world No.11 Sara Errani the eighth seed in Germany.
Ana leads her countrywoman Jankovic 8-3 in previous career meetings. On clay it's 2-1 to Ana, while the pair's last meeting was a 7-5, 6-3 victory for Ana at the 2013 Australian Open.
If she reaches round two, Ana will take on either world No.13 Flavia Pennetta or German wild card Andrea Petkovic.
Third seed Petra Kvitova could await in the quarter-finals, while second seed Simona Halep is a potential semi-final adversary.
The seeded players in the top half of the draw, whom Ana cannot face until the final, are No.1 Agnieszka Radwanska, No.4 Angelique Kerber, No.6 Maria Sharapova and No.8 Errani.
Click here for the full draw.