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Ana will take part in an exhibition event in Milan on 1 December. She will face Italy's Roberta Vinci in a one-set duel, then she will team up with four-time Grand Slam champion Maria Sharapova in a one-set doubles match against Vinci and top 10-ranked Italian Sara Errani.
The event follows a highly successful exhibition during the 2011 off-season, which saw Serena and Venus Williams take on Italians Francesca Schiavone and Flavia Pennetta.
"I've not yet been to Milan and visiting the city for the first time was a big motivation in me being part of the event," said Ana. "Everyone I know who has been there loves the city, so I'm really looking forward to visiting.
"I heard that last year's event with the Williams sisters, Schiavone and Pennetta was a great success and I'm sure it will be a lot of fun on 1 December."