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Ana has been drawn to face Russian world No.32 Elena Vesnina in the first round of the Internazionali BNL d'Italia, which begins in Rome on Sunday. It will be the first meeting between the pair.
Ninth seed Victoria Azarenka is waiting for the winner of that match in round two, while eighth seed Elena Dementieva is a potential third round opponent.
Ana could play world No.3 Dinara Safina in the quarter-finals, while No.2 seed Caroline Wozniacki and No.8 seed Agnieszka Radwanska are potential adversaries in the semi-finals.
The leading seeds in the top half of the draw, whom Ana could not meet until the final, are No.1 Serena Williams, No.4 Venus Williams, No.6 Svetlana Kuznetsova and No.7 Jelena Jankovic.
All of the world's top 10 players, if healthy, will be present in the Italian capital for this $2million Premier event.
Click here for the full draw.