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Ana will play Russian Nadia Petrova for a semi-final place.
Nadia Petrova made her breakthrough at the French Open two years ago when she defeated Monica Seles and Jennifer Capriati on a run to the semi-finals.
Ana beat Petrova in their only previous encounter. That came in Miami at the start of the year when Ana won 6-4, 7-5.
Ana's match will be first on Suzanne Lenglen Court.