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Ana is seeded ninth at the Rogers Cup Presented by National Bank, which begins in Montreal on Monday. She will face a qualifier in round one.
Should she reach the second round, another qualifier or China's Shuai Zhang will await. In the third round Ana could face compatriot and seventh seed Jelena Jankovic.
Second seed Petra Kvitova, who won Wimbledon last month, is a possible quarter-final opponent, while No.3 Agnieszka Radwanska and No.8 Victoria Azarenka are possible adversaries in the semi-finals.
The leading seeds in the top half of the draw, whom Ana cannot face until the final, are No.1 Serena Williams, No.4 Maria Sharapova, No.5 Eugenie Bouchard and No.6 Angelique Kerber.
The only absentees among the world's top 20 are No.2 Na Li (injured) and No.3 Simona Halep (did not enter).
Click here for the full draw.