| SPAIN 2 d SERBIA 1 | | | |
| round | doubles | against | score |
| Rubber 3 | Ana Ivanovic(SRB)/Novak Djokovic(SRB) | Fernando Verdasco (ESP) /Anabel Medina Garrigues (ESP) | 4-6 5-7 |
| Rubber 2 | | Anabel Medina Garrigues (ESP) | 4-6 7-6(3) 2-6 |
| | | |
| SERBIA 3 d GERMANY 0 | | | |
| round | doubles | against | score |
| Rubber 3 | Ana Ivanovic(SRB)/Novak Djokovic(SRB) | Thanasi Kokkinakis(AUS)/Tatjana Malek (GER) | 6-2 7-5 |
| Rubber 2 | | Tatjana Malek (GER) | 6-0 6-1 |
| | | |
| SERBIA 2 d AUSTRALIA 1 | | | |
| round | doubles | against | score |
| Rubber 3 | Ana Ivanovic(SRB)/Novak Djokovic(SRB) | Bernard Tomic (AUS) /Ashleigh Barty (AUS) | 6-4 6(8)-7 [10-6] |
| Rubber 2 | | Ashleigh Barty (AUS | 6-2 6-3 |
| | | |
| SERBIA 2 d ITALY 1 | | | |
| round | doubles | against | score |
| Rubber 3 | Ana Ivanovic(SRB)/Novak Djokovic(SRB) | Francesca Schiavone (ITA) /Andreas Seppi (ITA) | 6(4)-7 4-6 |
| Rubber 1 | | Francesca Schiavonne (ITA) | 6-0 6-4 |
